Abstract In view of the difficulties faced by teachers in designing silicate materials, three teaching materials corresponding to ceramics, glass and cement are developed: Shijiahe red pottery cup, Luoyang float glass and Baihetan dam, including 2 original experiments, 7 materials and 14 original questions. This material can be used in the new class of silicate materials or the review class of silicate materials, and can also provide a reference for the order maker of the original problem. The selection of materials follows the concept of moral education, cultivates students’ patriotism and improves their advanced thinking ability.