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化学史与化学史教育
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| 氢键概念的形成和发展 |
| 胡琪琳, 袁振东* |
| 河南师范大学化学化工学院 河南新乡 453007 |
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| Formation and Development of the Concept of Hydrogen Bond |
| HU Qi-Lin, YUAN Zhen-Dong* |
| Institute of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China |
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摘要：1902年,瑞士化学家维尔纳对氯化铵结构的解释为氢键概念的形成奠定了基础。1920年,美国化学家拉提麦尔和罗德布什首先认识了水中的氢键:2个八隅体所持的氢核构成的“弱键(weak bond)”。1928年,美国化学家鲍林在解释[FHF]-的结构时首次使用“氢键(hydrogen bond)”一词,但并未对氢键的概念进行明确定义。1939年,鲍林在《化学键的本质》中明确提出了氢键的概念,并解释了氢键的性质,自此,氢键的概念正式形成。近年来,科学家经过深入研究发现了氢键的新类型:π型氢键、双氢键、金属氢键和单电子氢键。随着科学思想和科学技术的发展,关于氢键的认识也会越来越深入。
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| 关键词： 氢键的概念,
拉提麦尔,
罗德布什,
鲍林,
氢键的新类型
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通讯作者:
* E-mail:yuanzhendong64@126.com
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| 引用本文: |
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胡琪琳, 袁振东. 氢键概念的形成和发展[J]. 化学教育（中英文）, 2023, 44(1): 123-128
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