化学史与化学史教育
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凸显哲学思维与科学方法的氟单质制备及发现*
刘环环1 , 王长号2 , 高胜利2 , 胡满成2 , 马艺2**
1.陕西师范大学基础实验教学中心 陕西西安 710062; 2.陕西师范大学化学化工学院 陕西西安 710119
Preparation and Discovery of Fluorine Highlight Philosophical Thinking and Scientific Methods
LIU Huan-Huan1 , WANG Chang-Hao2 , GAO Sheng-Li2 , HU Man-Cheng2 , MA Yi2**
1. Basic Experimental Teaching Center, Shaanxi Normal University, Xi'an 710062, China; 2. School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China
摘要: 氟作为卤族元素的首个元素被广泛应用于农药、医药、原子能、火箭技术、石油精炼等方面,在人类社会生产生活的诸多领域起到不可取代的作用。本文主要通过介绍氟单质的首次制备及在自然界中首次发现的过程等内容,普及更新一些氟化学知识。通过氟单质典型事件的叙述体现哲学思想和科学研究方法在化学中的应用。
关键词: 氟气 ,
制备 ,
萤石 ,
安托宗石
基金资助: *陕西师范大学教改项目(21JG03)
通讯作者:
** E-mail: mayi@snnu.edu.cn
引用本文:
刘环环, 王长号, 高胜利, 胡满成, 马艺. 凸显哲学思维与科学方法的氟单质制备及发现* [J]. 化学教育(中英文), 2023, 44(14): 125-129
[1]
[德]Kirsch P.当代有机氟化学 合成 反应 应用 实验. 朱士正,吴永明, 译.上海: 华东理工大学出版社,2006: 1-278
[2]
卿凤翎, 邱小龙. 有机氟化学. 北京: 科学出版社, 2007: 1-364
[3]
Uneyama K. Organofluorine chemistry. Boston: Springer, 2006
[4]
Hudlicky M. Fluorine chemistry for organic chemists. New York: Oxford University Press, 2000
[5]
Chambers R D. Fluorine in organic chemistry. Oxford: Balckwell, 2004
[6]
陈庆云. 自然杂志, 1979 (6): 26
[7]
Moissan H. C. R. Hebd. Seances Acad. Sci., 1886, 102: 1543-1544
[8]
Midgley T. Ind. Eng. Chem., 1937, 29 (2): 241-244
[9]
Herran N. Ambix, 2018, 65 (4): 407-408
[10]
Reed B C. Am. J. Phys., 2020, 88 (2): 108-114
[11]
Tressaud A. Fluorine: A paradoxical element. Amsterdam: Elsevier, 2019
[12]
张卜天. 中国科技史杂志, 2017, 38 (3): 339-345
[13]
Ampere A M. Ann. Phys. Chim., 1816, 2: 5
[14]
Partington J R. Mem. Proc. Manchester Lit. Phil. Soc., 1923, 67: 73
[15]
Margraff A. Memoirs Royal Academy of Sciences of Berlin, 1768, XXIV: 3
[16]
Scheele C W. Haushaltungskunst und Mechanik, 1771, 33: 122-139
[17]
Davy H. Philos. Trans. R. Soc. London, 1813, 103: 263-279
[18]
Weeks M E. J. Chem. Educ., 1932, 9 (11): 1915-1939
[19]
Toon R. Educ. Chem., 2011, 48 (5): 148
[20]
Gunne J S A D, Mangstl M, Kraus F. Angew. Chem. Int. Ed., 2012, 51 (31): 7847-7849
[21]
Vochten R, Esmans E, Vermeirsch W. Chem. Geol., 1977, 20: 253-263
[22]
Garnier J. C. R. Hebd. Seances Acad. Sci., 1901, 132: 95-96
[23]
Arribas A. Estud. Geol., 1964, 20: 149-169
[24]
Assadi P, Chaigneau M. C. R. Hebd. Seances Acad. Sci., 1962, 255: 2798
[25]
Asadi P. Phys. Status. Solidi., 1967, 20: K71
[26]
Christman R A, Brock M R, Pearson R C, et al. U S Geol. Surv. Bull., 1959: 1072
[27]
Heinrich E W, Anderson R J. Am. Mineral., 1965, 50: 1914-1920
[28]
Ellsworth H V. Econ. Geol. Rep. Geol. Surv. Can., 1932: 11
[29]
Sine F L. Univ. Toronto. Stud. Geo.l Ser., 1925, 20: 22-24
[30]
Iimori S. Rikagaku Kenkyusho Iho, 1932, 11: 1237-1243
[31]
Spence H S, Carnochan R K. Trans. Can. Inst. Min. Metall. Min. Soc. N S, 1930, 33: 43-48
[32]
Braithwaite R S W, Flowers W T, Haszeldine R N, et al. Min. Mag., 1973, 39: 401-411
[33]
Bill H, Calas G. Phys. Chem. Miner., 1978, 3 (2): 117-131
[34]
Dill H G, Weber B. Neues Jahrb Mineral Abh, 2010, 187 (2): 113-132
[35]
Schönbein C F. J. Prakt. Chem., 1861, 83: 86
[36]
Henrich F. Sitzungsber Phys-Med Soz Erlangen, 1914, 46: 1-14
[37]
Gilg H A. Extra-Lapis English, 2006, 9: 114-116
[38]
Dill H G, Füβl M, Weber B. Oberpfälzer Heimat, 2008, 53: 213-225
[39]
Harris R K, Becker E D, Cabral de Menezes S M, et al. Pure Appl. Chem., 2008, 80: 59-84
[40]
Chan J C, Eckert H. J. Non-Cryst Solids, 2001, 284: 16-21
[41]
Nebgen J W, Rose W B, Metz F I. J. Mol. Spectrosc., 1966, 20: 72-74
[42]
Hindermann D K. J. Chem. Phys., 1968, 48: 2017-2024
[43]
Avadhut Y S, Schneider D, Schmedt auf der Günne J. J. Magn. Reson., 2009, 201 (1): 1-6
[44]
Zanetti R, Bleloch A J, Grimshaw M P, et al. Philos. Mag. Lett., 1994, 69 (5): 285-290
[45]
Bennewitz R, Smith D, Reichling M. Phys. Rev. B, 1999, 59 (12): 8237-8246
[46]
Dill H G, Hansen B T, Weber B. Ore Geol. Rev., 2011, 40: 132-148
[47]
Magill J, Pfennig G, Galy J. Karlsruher Nuklidkarte. Lage/Lippe: Haberbeck, 2006