化学·生活·社会
分子机器的设计与合成——2016年诺贝尔化学奖解读
李川
北京师范大学化学学院 北京 100875
Design and Synthesis of Molecular Machines: Understanding the Nobel Prize in Chemistry 2016
LI Chuan
College of Chemistry, Beijing Normal University, Beijing 100875, China
摘要： 法国斯特拉斯堡大学的让-皮埃尔·索维奇（Jean-Pierre Sauvage）和美国西北大学的弗雷泽·斯托达特（J.Fraser Stoddart）利用机械键设计了锁链分子机器——索烃和轮烷，荷兰格罗宁根大学的伯纳德·费林加（Bernard L.Feringa）基于不饱和键合成分子马达实现了分子机器的单向旋转，3位科学家因“设计、合成分子机器”而被授予2016年诺贝尔化学奖。
关键词： 分子机器 ,
诺贝尔化学奖 ,
索烃 ,
轮烷 ,
分子马达
通讯作者:
李川
E-mail: lichuanbnu@126.com
引用本文:
李川. 分子机器的设计与合成——2016年诺贝尔化学奖解读[J]. 化学教育（中英文）, 2017, 38(8): 1-8
[1]
诺贝尔官方网站.The Nobel Prize in Chemistry 2016[EB/OL].(2016-10-05).http://www.nobelprize.org/nobel_prizes/chemistry/laureates/2016/press.pdf
[2]
李昊,许曦晨,陈嘉伟,等.有机化学,2008,28(12):2057-2071
[3]
诺贝尔官方网站.Scientific Background on the Nobel Prize in Chemistry 2016[EB/OL].(2016-10-05).http://www.nobelprize.org/nobel_prizes/chemistry/laureates/2016/advanced-chemistryprize2016.pdf
[4]
诺贝尔官方网站.How molecules became machines[OB/L].(2016-10-05).https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2016/popular-chemistryprize2016.pdf (2016-10-05)
[5]
Wasserman E.Journal of the American Chemical Society,1960,82(16):4433-4434
[6]
Schill G,Lüttringhaus A.AngewandteChemie International Edition,1964,3(8):546-547
[7]
Schill G.European Journal of Inorganic Chemistry,1967,100(6):2021-2037
[8]
Vetter W,Schill G.Tetrahedron,1967,23(7):3079-3093
[9]
Harrison I T,Harrison S.Journal of the American Chemical Society,2002,89(22):5723-5724
[10]
Schill G,Zollenkopf H.European Journal of Organic Chemistry,1969,721(1):53-74
[11]
黄甫,赵伟,车延科,等.化学教育,2016,37(22):1-5
[12]
Dietrich-Buchecker C O,Sauvage J P,Kintzinger J P.Tetrahedron Lett.,1983,24(46):5095-5098
[13]
Anelli P L,Spencer N,Stoddart J F.Journal of the American Chemical Society,1991,113(13):5131-5133
[14]
Bissell R A,CÓ E,Kaifer A E,et al.Nature International Weekly Journal of Science,1994,369(6476):133-137
[15]
Aude Livoreil,Dietrichbuchecker C O,Jean Pierre Sauvage.Journal of the American Chemical Society,1994,116(20):9399-9400
[16]
Collin J P,Gavinã P,Sauvage J P.Chemical Communications,1996,17(17):2005-2006
[17]
Amabilino D B,Sauvage J P,Dietrich-Buchecker C O,et al.Journal of the American Chemical Society,1996,118(16):3905-3913
[18]
Ballardini R,Balzani V,Credi A,et al.AngewandteChemie International Edition,1996,35(9):978-981
[19]
Livoreil A,Sauvage J P,Armaroli N,et al.Journal of the American Chemical Society,1997,119(50):12114-12124
[20]
Raehm L,Kern J M,Sauvage J P.Chemistry-A European Journal,1999,5(11):3310-3317
[21]
Mobian P,Kern J M,Sauvage J P.AngewandteChemie International Edition,2004,43(18):2392-2395
[22]
Sauvage J P,Weiss J.Journal of the American Chemical Society,1985,107(21):6108-6110
[23]
Dietrich-Buchecker C O,Sauvage J P.AngewandteChemie International Edition,1989,28(2):189-192
[24]
Nierengarten J F,Dietrichbuchecker C O,Sauvage J P.AngewandteChemie,1994,116(1):9236-9238
[25]
Jiménez M C,Dietrich-Buchecker C,Sauvage J P.AngewandteChemie International Edition,2000,39(18):3284-3287
[26]
Badjic J D,Balzani V,Credi A,et al.Science,2004,303(5665):1845-1849
[27]
Huang T J,Brough B,Ho C M,et al.Applied Physics Letters,2004,85(22):5391-5393
[28]
Liu Y,Flood A H,Bonvallet P A,et al.Journal of the American Chemical Society,2005,127(27):9745-9759
[29]
Green J E,Choi J W,Boukai A,et al.Nature,2007,445(7126):414-417
[30]
Koumura N,Zijlstra R W,van Delden R A,et al.Nature,1999,401(6749):152-155
[31]
Vachon J,Carroll G T,Pollard M M,et al.Photochemical&Photobiological Sciences,2014,13(2):241-246
[32]
van Delden R A,ter Wiel M K,Pollard M M,et al.Nature,2005,437(7063):1337-1340
[33]
Fletcher S P,Dumur F,Pollard M M,et al.Science,2005,310(5745):80-82
[34]
Eelkema R,Pollard M M,Vicario J,et al.Nature,2006,440(7081):163
[35]
Kudernac T,Ruangsupapichat N,Parschau M,et al.Nature,2011,479(7372):208-211
[36]
Marlin D S,González C D,Leigh D A,et al.AngewandteChemie,2005,45(1):77-83
[37]
Pérez E M,Dryden D T,Leigh D A,et al.Journal of the American Chemical Society,2004,126(39):12210-12211
[38]
Balzani V,Stoddart J F.Proceedings of the National Academy of Sciences of the United States of America,2006,103(5):1178-1183
[39]
DvornikovsV,House B E,Kaetzel M,et al.Journal of the American Chemical Society,2003,125(27):8290-8301
[40]
Hernandez R,Tseng H R,Wong J W,et al.Journal of the American Chemical Society,2004,126(11):3370-3371
[41]
Feng M,Guo X,Lin X,et al.Journal of the American Chemical Society,2005,127(44):15338-15339
[42]
金涌.探索化学化工未来世界——值得为之付出一生(1).北京:清华大学出版社,2016:111
