|
化学史与化学史教育
|
|
|
|
|
|
| Friedel-Crafts:伟大的反应与伟大的合作者* |
| 李万方**, 邓钦月, 黄明贤** |
| 上海理工大学理学院化学系 上海 200093 |
|
| Friedel-Crafts: The Great Reaction and the Great Collaborators |
| LI Wan-Fang**, DENG Qin-Yue, HUANG Ming-Xian** |
| Department of Chemistry,College of Science, University of Shanghai for Science and Technology, Shanghai 200093, China |
|
|
| 文章导读 |
|
|
摘要：傅克反应(Friedel-Crafts Reaction)是迄今为止最古老、应用最长久的碳-碳键形成反应之一,广泛应用于医药、染料、石油等化学工业的各个分支。自1877年被发现以来,傅克反应已经发展成为最经典的有机反应之一,被写进现代有机化学教科书。跟其他重大化学发现类似,傅克反应的发现过程也充满着惊喜和意外,折射出化学家敏锐的洞察力和非同寻常的逻辑推理能力。本文通过整理一些早期的国内外文献和相关化学史料,简述了傅克反应发现的历史背景、发现过程,回顾了两位化学家查理斯·傅列德尔(Charles Friedel)和杰姆斯·克拉夫茨(James Crafts)的一些重要成长经历以及他们接近40年的伟大合作历程。
|
|
| 关键词： 傅克反应,
化学家,
发现,
历史
|
|
|
| 基金资助:*国家自然科学青年基金(21901163) |
|
通讯作者:
**E-mail:lwf@usst.edu.cn;hmx@usst.edu.cn
|
| 引用本文: |
|
李万方, 邓钦月, 黄明贤. Friedel-Crafts:伟大的反应与伟大的合作者*[J]. 化学教育（中英文）, 2021, 42(10): 106-111
|
|
| [1] |
Weissermel K, Arpe H-J.Aromatics—Production and Conversion//Industrial Organic Chemistry. Germany: Wiley, 2003: 313-336
|
| [2] |
Reddy V P, Prakash G K S.Friedel-Crafts Reactions//Kirk-Othmer Encyclopedia of Chemical Technology. Germany: Wiley, 2013: 1-49
|
| [3] |
Niaz M. Chemistry Education and Contributions from History and Philosophy of Science. Switzerland: Springer, 2016
|
| [4] |
Hudson J. Organic Chemistry since 1860//The History of Chemistry. New York: Chapman & Hall, 1992: 138-159
|
| [5] |
Brock W H. The Fontana History of Chemistry. New York: Harper Press, 2012: 198-227
|
| [6] |
Frankland E. Quarterly Journal of the Chemical Society of London, 1850, 2(3): 263-296
|
| [7] |
Werner H. The Nineteenth Century: A Sequence of Accidental Discoveries//Landmarks in Organo-Transition Metal Chemistry. Germany: Springer, 2008: 69-84
|
| [8] |
Calloway N O. Chemical Reviews,1935, 17(3): 327-392
|
| [9] |
Kürti L, Czakó B. Wurtz Coupling//Strategic Applications of Named Reactions in Organic Synthesis. San Diego: Elserver, 2005: 498-499
|
| [10] |
Zincke T. Berichte der Deutschen Chemischen Gesellschaft, 1869, 2(1): 737-740
|
| [11] |
Zincke T. Justus Liebigs Annalen der Chemie, 1871, 159(3): 367-383
|
| [12] |
Grucarevic S, Merz V. Berichte der Deutschen Chemischen Gesellschaft, 1873, 6(2): 1238-1246
|
| [13] |
Crafts J M. Journal of the Chemical Society, Transactions, 1900, 77:993-1019
|
| [14] |
Willemart A. Journal of Chemical Education, 1949, 26(1): 3-9
|
| [15] |
Friedel C, Crafts J. Bulletin de la Société Chimique de France, 1874, 21:435
|
| [16] |
Friedel C, Crafts J. Comptes Rendus, 1877, 84:1392-1450
|
| [17] |
Ashdown A A. Industrial and Engineering Chemistry 1927, 19(1): 1063-1065
|
| [18] |
Oakes E H. Encyclopedia of World Scientists.New York: Infobase Publishing, 2007: 253
|
| [19] |
Ashdown A A. Journal of Chemical Education, 1928, 5(8): 911-921
|
| [20] |
Nandi K K. Catalysis in Green Chemistry and Engineering, 2018, 1(2): 149-153
|
| [21] |
Olah G A. Friedel-Crafts Chemistry. New York: Wiley, 1973
|
| [22] |
Olah G A. A Life of Magic Chemistry. New York: Wiley, 2001
|
|
|
|
