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问题讨论与思考
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| 烯烃的羟汞化脱汞:还原脱汞机理* |
| 杨占会**, 许家喜 |
| 北京化工大学化学学院 北京 100029 |
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| Alkene Oxymercuration-Demercuration: Detailed Mechanism for Demercuration |
| YANG Zhan-Hui**, XU Jia-Xi |
| College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China |
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摘要：介绍了不同时期提出的还原脱汞机理,包括Bordwell和Douglass的协同机理、Pasto和Gontarz的自由基笼机理、Whitesides和Filippo的自由基链机理和Quirk和Whitesides等人完善的自由基链机理。对还原脱汞机理的介绍完善了现行教科书中的机理,有利于学生学习完整的有机化学知识和机理,培养正确的有机化学研究理念。
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| 关键词： 羟汞化,
还原脱汞,
机理,
自由基笼,
自由基链
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| 基金资助:*“有机化学”和“中级有机化学”一流课程建设项目 |
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通讯作者:
**E-mail: zhyang@mail.buct.edu.cn
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| 引用本文: |
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杨占会, 许家喜. 烯烃的羟汞化脱汞:还原脱汞机理*[J]. 化学教育（中英文）, 2023, 44(2): 117-122
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