化学·生活·社会
β -酮烯胺基COFs TpPa-1及其复合材料的研究进展
杜晋君, 刘仲鹤, 韩槐泽, 闫宝林, 方兵, 戴玉华*
北京石油化工学院新材料与化工学院 特种弹性体复合材料北京市重点实验室 北京 102617
Research Progress of β -Ketoenamine COFs TpPa-1 and Its Composites
DU Jin-Jun, LIU Zhong-He, HAN Huai-Ze, YAN Bao-Lin, FANG Bing, DAI Yu-Hua*
College of New Materials and Chemical Engineering,Beijing Key Laboratory of Special Elastomeric Composite Materials, Beijing Institute of Petrochemical Technology,Beijing 102617,China
摘要： 共价有机框架材料(COFs)是一种由C、H、N、O等轻质元素组成并通过共价键连接的新型聚合物材料,具有高比表面积、高孔隙率、低密度、孔道有序、结构可控等优点,受到众多研究人员的密切关注。结合国内外学者的近期研究成果,总结了β -酮烯胺基COFs TpPa-1及其复合材料的制备方法,综述了TpPa-1及其复合材料在分离、吸附、催化、储能等领域的应用研究进展,并对存在的问题提出了相应的建议。
关键词： 共价有机框架 ,
TpPa-1 ,
合成 ,
应用
收稿日期: 2025-05-07
通讯作者:
*E-mail: 0020040662@bipt.edu.cn
引用本文:
杜晋君, 刘仲鹤, 韩槐泽, 闫宝林, 方兵, 戴玉华. β -酮烯胺基COFs TpPa-1及其复合材料的研究进展[J]. 化学教育（中英文）, 2026, 47(6): 1-13
[1]
Kandambeth S,Mallick A,Lukose B,et al.Journal of the American Chemical Society,2012,134(48):19524-19527
[2]
Côté A P,Benin A I,Ockwig N W,et al.Science,2005,310(5751):1166-1170
[3]
El-Kaderi H M,Hunt J R,Mendoza-Cortés J L,et al.Science,2007,316(5822):268-272
[4]
宋卅楠.高分子骨架材料的制备及其碘吸附性能研究.长春:吉林大学博士学位论文,2021
[5]
Biswal B P,Chandra S,Kandambeth S,et al.Journal of the American Chemical Society,2013,135(14):5328-5331
[6]
边宇,张百超,郑红.化工进展.2022,41(9):4866-4883
[7]
Li Y,Liu M,Wu J,et al.Frontiers of Optoelectronics,2022,15(1):38
[8]
Wei H,Chai S Z,Hu N T,et al.Chemical Communications,2015,51(61):12178-12181
[9]
Guo L C,Zhang Q Y,Yu Z W,et al.Chemistry of Materials,2023,35(14):5648-5656
[10]
Zhang J,Cheng C,Guan L J,et al.Journal of the American Chemical Society,2023,145(40):21974-21982
[11]
Peng Y W,Wong W K,Hu Z G,et al.Chemistry of Materials,2016,28(14):5095-5101
[12]
Jia S P,Liu Y J,Hao L Q,et al.Journal of the American Chemical Society,2023,145(48):26266-26278
[13]
Dai B L,Hu Y J,Ding Y D,et al.Desalination,2024,570:117083
[14]
Hao S,Zhang T,Fan S,et al.Chemical Engineering Journal,2021,421:129750
[15]
Wang R,Shi X S,Xiao A K,et al.Journal of Membrane Science,2018,566:197-204
[16]
Liu Q,Basel N,Li L,et al.Journal of Membrane Science,2022,647:120296
[17]
Mao C Y,Zhao S,He P P,et al.Chemical Engineering Journal,2021,414:128929
[18]
Yang G H,Zhang Z,Yin C C,et al.Journal of Polymer Science,2022,60(21):2999-3008
[19]
Liu Q,Huang P,Xu N,et al.Separation and Purification Technology,2024,341:126881
[20]
Wang J Q,Xu W Y,Xu F,et al.Journal of Membrane Science,2024,695:122470
[21]
Yang G H,Zhang Z,Yin C C,et al.Journal of Membrane Science,2022,661:120944
[22]
Fan Q F,Li Z X,Li M Z,et al.Separation and Purification Technology,2024,343:127167
[23]
Yang H,Wu H,Xu Z,et al.Journal of Membrane Science,2018,561:79-88
[24]
Ma X,Sun N,Li Z G,et al.Advanced Functional Materials,2024,34(19):2312203
[25]
Xiao A K,Zhang Z,Shi X S,et al.ACS Applied Materials & Interfaces,2019,11(47):44783-44791
[26]
Ding C H,Breunig M,Timm J,et al.Advanced Functional Materials,2021,31(49):2106507
[27]
Shi X S,Xiao A K,Zhang C X,et al.Journal of Membrane Science,2019,576:116-122
[28]
Zhang Z D,Li H,Cui J G,et al.Journal of Cleaner Production,2023,384:135595
[29]
Lai W,Shan L L,Bai J,et al.Chemical Engineering Journal,2022,450:137965
[30]
Wang M D,Wang Y T,Zhao J Y,et al.Angewandte Chemie-International Edition,2023,62(13):e202219084
[31]
Pan Y,Liu H H,Huang Z Q,et al.Angewandte Chemie-International Edition,2024,63(4):e202316315
[32]
马鹏程,单斌,王新波.精细化工,2025,42(3):492-507
[33]
许方依,彭宇,宋君杰,等.膜科学与技术,2023,43(5):136-149
[34]
Siow W J S,Chong J Y,Ong J H,et al.Angewandte Chemie-International Edition,2024,63(32):e202406830
[35]
Zou C C,Li Q Q,Hua Y Y,et al.ACS Applied Materials & Interfaces,2017,9(34):29093-29100
[36]
Xu H Q,Feng W Y,Yuan Y,et al.Chinese Journal of Chemical Engineering,2022,43:152-160
[37]
Tang Y C,Feng S,Fan L L,et al.Separation and Purification Technology,2019,223:10-16
[38]
Fan H W,Peng M H,Strauss I,et al.Nature Communications,2021,DOI:10.1038/s41467-020-20298-7
[39]
Zhang H,Li X D,Xiao C M,et al.Separation and Purification Technology,2022,302:122147
[40]
Yuan Y,Yang Y J,Meihaus K R,et al.Nature Chemistry,2023,15:1599-1606
[41]
Li K Y,Luan T X,Wang Z Y,et al.ACS Applied Nano Materials,2022,5(10):15228-15236
[42]
Zhong X,Lu Z P,Liang W,et al.Environmental Science-Nano,2020,7(11):3303-3317
[43]
Mei D C,Yan B.Advanced Functional Materials,2024,34(14):2313314
[44]
He S J,Zeng T,Wang S H,et al.ACS Applied Materials & Interfaces,2017,9(3):2959-2965
[45]
Wang W,Jia Y,Zhou S X,et al.Journal of Hazardous Materials,2023,460:132522
[46]
Wang W,Deng S B,Ren L,et al.ACS Applied Materials & Interfaces,2018,10(36):30265-30272
[47]
Guo X D,Yin D G,Khaing K K,et al.Inorganic Chemistry,2021,60(20):15557-15568
[48]
Khaing K K,Yin D G,Ouyang Y G,et al.Inorganic Chemistry,2020,59(10):6942-6952
[49]
Li L Q,Yin D G,Guo X D.New Journal of Chemistry,2021,45(35):15789-15800
[50]
Wang J,Yin D G,Guo X D,et al.Langmuir,2022,38(16):4680-4691
[51]
Yang R G,Fu Y M,Wang H N,et al.Chemical Engineering Journal,2022,450:138040
[52]
Jiang S D,Niu H Y,Sun Q,et al.Journal of Materials Chemistry A,2024,12(19):11416-11423
[53]
Wang L-J,Dong P-Y,Zhang G,et al.Energy & Fuels,2023,37(9):6323-6347
[54]
Zhang H Y,Yang Y,Li C C,et al.Journal of Materials Chemistry A,2021,9(31):16743-16750
[55]
Dang Q,Huang H L,Li L Y,et al.Chemistry of Materials,2021,33(14):5690-5699
[56]
Xue P,Pan X,Huang J M,et al.ACS Applied Materials & Interfaces,2021,13(50):59915-59924
[57]
Zhang F M,Sheng J L,Yang Z D,et al.Angewandte Chemie-International Edition,2018,57(37):12106-12110
[58]
Chen C X,Xiong Y Y,Zhong X,et al.Angewandte Chemie-International Edition,2022,61(3):e202114071
[59]
Hu H J,Zhang X Y,Zhang K L,et al.Advanced Energy Materials,2024,14(11):2303638
[60]
Wang H,Qian C,Liu J,et al.Journal of the American Chemical Society,2020,142(10):4862-4871
[61]
Yang D,Li Z G,Zhang X H,et al.Nano Research,2024,17(3):1027-1034
[62]
Gao M Y,Li C C,Tang H L,et al.Journal of Materials Chemistry A,2019,7(35):20193-20200
[63]
Dong P Y,Zhang A,Cheng T,et al.Chinese Journal of Catalysis,2022,43(10):2592-2605
[64]
Zhang Y P,Han W,Yang Y,et al.Chemical Engineering Journal,2022,446:137213
[65]
Xu M L,Lu M,Qin G Y,et al.Angewandte Chemie-International Edition,2022,61(44):e202210700
[66]
Li C C,Gao M Y,Sun X J,et al.Applied Catalysis B-Environmental,2020,266:118586
[67]
Yan H,Liu Y H,Yang Y,et al.Chemical Engineering Journal,2022,431:133404
[68]
Yao Y H,Yang Y,Wang Y,et al.Journal of Colldid and Interface Science,2022,608:2613-2622
[69]
Chen Y,Yang D,Gao Y C,et al.Research,2021,2021:1-12
[70]
Zhang M Y,Qin J Q,Rajendran S,et al.Chemsuschem,2018,11(24):4226-4236
[71]
Sun Y L,Jin D,Sun Y,et al.Journal of Materials Chemistry A,2018,6(19):9124-9131
[72]
Lin Z H,Wang Y,Li Y,et al.Energy Storage Materials,2022,53:917-926
[73]
Loo K L,Ho J W,Chung C H,et al.Journal of Materials Chemistry A,2024,12(13):7875-7885
[74]
Lakraychi A E,Picton E S,Liang Y L,et al.ACS Energy Letters,2023,8(12):5032-5040
[75]
Cai J B,Wang J L,Yu X,et al.Journal of Materials Chemistry A,2023,11(46):25692-25702
[76]
Lin T Y,Wang H Y,Du X H,et al.Electrochimica Acta,2022,412:140156
[77]
Zhang C F,Li W,Guo Z,et al.Progress in Organic Coatings,2023,177:107441
[78]
Li W,Zhang X Y,Zhang C Y,et al.Progress in Organic Coatings,2021,157:106299
[79]
Jing L P,Cheng C L,Wang B,et al.Langmuir,2023,39(1):597-609
[80]
Zhao Z P,Feng H M,Qin D,et al.ACS Applied Polymer Materials,2023,5(3):2124-2135
[81]
Liu C,Wang W,Zhang M T,et al.Chemical Engineering Journal,2022,430:132663
[82]
Wang Z Q,Wang X,Li C,et al.Cell Reports Physical Science,2024,5(3):101845
[83]
Wang J M,Lian X,Yan B.Inorganic Chemistry,2019,58(15):9956-9963
[84]
Zhou L,Yang R J,Li X R,et al.Journal of the American Chemical Society,2023,145(43):23727-23738
[85]
Zheng J T,Huang S Y,Tong Y J,et al.Analytica Chimica Acta,2020,1137:28-36
[86]
Wang J M,Zhao L M,Yan B.ACS Applied Materials & Interfaces,2020,12(11):12990-12997
[87]
Wang X Y,Yin H Q,Yin X B.ACS Applied Materials & Interfaces,2020,12(18):20973-20981
[88]
Liu L,Meng W K,Zhou Y S,et al.Chemical Engineering Journal,2019,356:926-933
[89]
Wen L,Wu P,Wang L L,et al.Analytical Methods,2020,12(19):2434-2442
[90]
Zhang M S,Li L Y,Lin Q M,et al.Journal of the American Chemical Society,2019,141(13):5154-5158
[91]
Liu Y L,Fu J C,Zhu Y H,et al.Chemsuschem,2024,17(11):e202400030
[92]
He X C,Ji W L,Xing S J,et al.Talanta,2024,268:125283
