化学·生活·社会
碱金属氢化物的结构、性质、制备及应用*
袁文玉1 , 王颖1 , 张航1 , 李淑妮1 , 翟全国1** , 高胜利2**
1.陕西师范大学化学化工学院 陕西西安 710119;
Structures,Properties,Preparation and Applications of Alkali Metal Hydrides
YUAN Wen-Yu1 , WANG Ying1 , ZHANG Hang1 , LI Shu-Ni1 , ZHAI Quan-Guo1** , GAO Sheng-Li2**
1. School of Chemistry and Chemical Engineering,Shaanxi Normal University,Xi'an 710119,China;
摘要： 碱金属氢化物是一类典型的离子型化合物。依据文献,详述碱金属氢化物的结构、制备、性质和应用等方面的特殊性,并突出“构效关系”。
关键词： 碱金属氢化物 ,
结构 ,
制备 ,
性质 ,
应用
收稿日期: 2024-08-30
基金资助: *教育部“西部高校化学专业(师范)虚拟教研室”建设经费;陕西师范大学本科教育教学改革“揭榜挂帅”项目(24JBGS28)
通讯作者:
** 翟全国,E-mail: zhaiqg@snnu.edu.cn;高胜利,E-mail:gaoshengli729@126.com
引用本文:
袁文玉, 王颖, 张航, 李淑妮, 翟全国, 高胜利. 碱金属氢化物的结构、性质、制备及应用* [J]. 化学教育（中英文）, 2025, 46(10): 10-18
[1]
Pauling L.Journal of the American Chemical Society,1932,54(9):3570-3575
[2]
Dutta C M,Nordlander P,Kimura M,et al.Physical Review A,2001,63(2):022709(1-5)
[3]
Dalgarno A,Kirby K,Stancil P C.Astrophysical Journal,1996,458:397-400
[4]
Bellini M,De Natale P,Inguscio M,et al.Astrophysical Journal,1994,424:507-509
[5]
Curik R,Greene C H.Physical Review Letters,2007,98(17):173201(1-4)
[6]
Croft H,Dickinson A S,Gadéa F X.Journal of Physics B,1999,32(1):81-94
[7]
Mendez L,Cooper I L,Dickinson A S,et al.Journal of Physics B,1990,23(16):2797-2810
[8]
Rajpurohit A S,Reyle C,Allard F,et al.Astronomy & Astrophysics,2013,556:A15(1-14)
[9]
Magnier S.Journal of Physical Chemistry A,2005,109(24):5411-5414
[10]
赵东霞,黄艳伟.辽宁师范大学学报:自然科学版,2010,33(2):201-204
[11]
Haynes W M.CRC handbook of chemistry and physics.93rd ed.Boca Raton:CRC Press Inc.,2012-2013
[12]
Baroni S,De Gironcoli S,Dal Corso A,et al.Reviews of Modern Physics,2001,73(2):515-518
[13]
Einarsdotter K,Sadigh B,Grimvall G,et al.Physical Review Letters,1997,79(11):2073-2078
[14]
Craievich P J,Weinert M,Sanchez J M,et al.Physical Review Letters,1994,72(19):3076-3079
[15]
Zhang J Y,Zhang L J,Cui T,et al.Journal of Physics:Condensed Matter,2007,19(42):425218
[16]
Priyanga G S,Meenaatci A A,Palanichamy R R,et al.Computational Materials Science,2014,84:206-216
[17]
Perrot F.Physica Status Solidi B,1976,77(2):517-525
[18]
Loubeyre P,Le Toullec R,Hanfland M,et al.Physical Review B,1998,57(17):10403-10406
[19]
Errea I,Martinez-Canales M,Bergara A.Physical Review B,2008,78(17):172501
[20]
Gramsch S A,Cohen R E,Savrasov S Y.American Mineralogist,2003,88(2/3):257-261
[21]
Zintl E T,Harder A.Zeitschrift für Physikalische Chemie,Abt.B,1931,14(1):265-284
[22]
Ghandehari K,Luo H,Ruoff A L,et al.Physical Review Letters,1995,74(12):2264-2267
[23]
Duclos S J,Vohra Y K,Ruoff A L,et al.Physical Review B,1987,36(14):7664-7667
[24]
Hochheimer H D,Strössner K,Hönle W,et al.Zeitschrift für Physikalische Chemie,1985,143(143):139-144
[25]
Sullivan E A,Wade R C.Kirk-Othmer encylopedia of chemical technology.3rd ed.New York:John Wiley & Sons,1980:772-773
[26]
刘通.纳米碱金属氢化物高化学反应活性的研究.大连:辽宁师范大学硕士学位论文,2005
[27]
Hurd D T.氢化物化学导论.燕正曜,译.北京:科学出版社,1958:25-27
[28]
Hansley V L,Keith M F.Process for preparing sodium hydride:USA,US3222288A,1965-12-07
[29]
Landa S,Lebl B,Mostecky J,et al.Process for the production of sodium hydride:USA,US3535078A,1970-10-20
[30]
Walker J A.A text-book of inorganic chemistry.Vol.2. London:ScienceMadness,1924:190-191
[31]
Ibrahim A,Paskevicius M,Humphries T D,et al.Inorganic Chemistry,2024,63(6):3047-3056
[32]
NurdRage.Make Sodium Metal with Menthol(and a bunch of other stuff…)[EB/OL].(2019-02-14)[2024-07-29].https://www.youtube.com/watch？v=BsNoiFj3wlw
[33]
Herold A.Comptes Rendus,1949,228:686-688
[34]
Guérard D,Elalem N E,Hadigui S E,et al.Journal of the Less-Common Metals,1987,131:173-180
[35]
Elansari L,Antoine L,Janot R,et al.Journal of Alloys and Compounds,2001,329(1/2):L5-L8
[36]
Gaffet E.Materials Science and Engineering A,1991,132:181-193
[37]
Chen Y,Williams J S.Journal of Alloys and Compounds,1995,217(2):181-184
[38]
Tessier P,Akiba E.Journal of Alloys and Compounds,2000,302(1/2):215-217
[39]
Qian C T,Zhu D M,Gu Y.Journal of Organometallic Chemistry,1991,401(1/2):23-29
[40]
Sloan M F,Matlack A S,Breslow D S.Journal of the American Chemical Society,1963,85(24):4014-4018
[41]
Stern R,Hillion G,Sajus L.Tetrahedron Letters,1969,10(20):1561-1566
[42]
Dozzi G,Cucinella S,Mazzei A.Journal of Organometallic Chemistry,1979,164(1):1-10
[43]
Zhang Y P,Liao S J,Xu Y,et al.Journal of Organometallic Chemistry,1990,382(1/2):69-76
[44]
钱延龙,陈新滋.金属有机化学与催化.北京:化学工业出版社,1997:675
[45]
Pi R,Friedl T,Schleyer P V R,et al.Journal of Organic Chemistry,1987,52(19):4299-4303
[46]
Gilman H,Jacoby A L,Ludeman H.Journal of the American Chemical Society,1938,60(10):2336-2338
[47]
Ashby E C,Noding S A.Journal of Organic Chemistry,1980,45:1041-1045
[48]
Klusener P A,Brandsma L,Verkruijsse H D,et al.Angewandte Chemie International Edition,1986,25(5):465-466
[49]
Bank S,Lois T A.Journal of the American Chemical Society,1968,90(16):4505-4506
[50]
廖世健,孔巍,刘和众,等.化学学报,1985,43(8):752-756
[51]
Zhang Y P,Liao S J,Xu Y.Journal of Molecular Catalysis,1993,84(3):211-221
[52]
李伟娜.纳米尺寸NaH的化学反应活性及纳米尺寸LiH和KH的热稳定性与化学反应活性.沈阳:辽宁师范大学硕士学位论文,2001
[53]
吴强.纳米碱金属氢化物的性能应用及纳米镧系金属粉末的制备.沈阳:辽宁师范大学硕士学位论文,2003
[54]
Bogdanović B.Angewandte Chemie International Edition,1985,24(4):262-273
[55]
Van Tamelen E E,Fechter R B.Journal of the American Chemical Society,1968,90(24):6854
[56]
Rumble J,Bruno T J,Doa M J.CRC handbook of chemistry and physics.104th ed.Boca Raton:CRC Press,2023:5-60
[57]
Smith M B,Bass Jr G E.Journal of Chemical & Engineering Data,1963,8(3):342-346
[58]
张青莲.无机化学丛书 第一卷.北京:科学出版社,1984:395-396
[59]
Ong D Y,Pang J H,Chiba S.Journal of Synthetic Organic Chemistry,Japan,2019,77(11):1060-1069
[60]
Terada K,York B L.Preparation of aluminum hydride:USA,US3869545A,1975-03-04
[61]
Rathman T L,Schwindeman J A,Granger E J,et al.Process for the preparation of lithium aluminum hydride in etheral solvents:USA,US5730952A,1998-03-24
[62]
Finholt A E,Bond A C,Wilzbach K E,et al.Journal of the American Chemical Society,1947,69(11):2692-2696
[63]
Bogdanović B,Schwickardi M.Journal of Alloys and Compounds,1997,253:1-9
[64]
Zidan R A,Takara S,Hee A G,et al.Journal of Alloys and Compounds,1999,285(1/2):119-122
[65]
Zaluska A,Zaluski L,Ström-Olsen J O.Journal of Alloys and Compounds,1999,288(1/2):217-225
[66]
Zaluski L,Zaluska A,Ström-Olsen J O.Journal of Alloys and Compounds,1999,290(1/2):71-78
[67]
Vajo J J,Skeith S L,Mertens F,et al.Journal of Alloys and Compounds,2005,390(1/2):55-61
[68]
Xu Q,Wang R,Kiyobayashi T,et al.Journal of Power Sources,2006,155(2):167-171
[69]
Yu P,Chua Y S,Cao H J,et al.Journal of Energy Chemistry,2014,23(4):414-419
