化学·生活·社会
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硫的同素异形体*
曹宝月1** , 崔孝炜1 , 乔成芳1 , 周春生1 , 强元圆1 , 王跳跳1 , 高胜利1,2**
1.商洛学院化学工程与现代材料学院 陕西商洛 726000;
2.西北大学化学与材料科学学院 陕西西安 710069
The Allotropes of Sulfur
CAO Bao-Yue1** , CUI Xiao-Wei1 , QIAO Cheng-Fang1 , ZHOU Chun-Sheng1 , QIANG Yuan-Yuan1 , WANG Tiao-Tiao1 , GAO Sheng-Li1,2**
1. College of Chemical Engineering and Modern Materials, Shangluo University, Shangluo 726000, China;
2. College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China
摘要: 硫是固态同素异形体数量最多的元素。但就单质硫的同素异形体而言,教材中并没有详细概述。根据硫化学的研究进展,全面考察了硫的同素异形体的种类,讨论了它们的制备、晶体结构及其相互转化,着重体现了科学技术对其同素异形体扩展的重要作用,完善了硫同素异形体在教学中的深入介绍。同时,也体现了科学研究对本科教学内容改革的推进作用。
关键词: 硫 ,
同素异形体 ,
结构 ,
制备 ,
应用
基金资助: * 国家精品课程“无机化学和分析化学”(教高函 (2007)20 号);国家级教学团队“无机化学和分析化学基础课教学团队”(教高函(2007)23号);陕西省课程思政示范课和陕西省课程思政示范教学团队“无机化学”(陕教(2021)64号);陕西省线下一流本科课程“无机化学”(陕教高办(2019)36号)
通讯作者:
** E-mail: cby0406@163.com; gaoshengli729@126.com
引用本文:
曹宝月, 崔孝炜, 乔成芳, 周春生, 强元圆, 王跳跳, 高胜利. 硫的同素异形体* [J]. 化学教育(中英文), 2022, 43(4): 8-26
[1]
徐心诚. 生物学通报,1990(8): 19-20, 27
[2]
尚志钧.神农本草经校注.北京: 学苑出版社, 2008
[3]
许长安.职业医学, 1986(6): 40-42
[4]
范巧玲, 姜雪峰.化学教育(中英文), 2019, 40(1): 2-6
[5]
Thompson D W. European History Quarterly, 1995(2): 163-180
[6]
张克强, 季民, 李军幸, 等. 含硫化物废水生物处理过程中单质硫的形成特性//首届全国农业环境科学学术研讨会论文集. 2005:357-361
[7]
金伟建. 化学教学, 1991 (1): 27-29
[8]
杨奇, 陈三平, 谢钢, 等. 中国大学教学, 2016 (4): 31-35
[9]
张文广, 游明祥, 彭思艳, 等. 化学教育(中英文), 2019, 40 (12): 38-41
[10]
要红昌, 李一珂, 武杰, 等. 大学化学, 2020, 35 (8): 56-61
[11]
Steudel R, Eckert B. Solid Sulfur Allotropes Sulfur Allotropes. In Elemental Sulfur and Sulfur-Rich Compounds I. Berlin: Springer Berlin Heidelberg, 2003: 1-80
[12]
Meyer B. Chemical Reviews, 1976 (3): 367-388
[13]
Aten H. Zeitschrift für Physikalische Chemie, 1914, 86(1): 1-35
[14]
Ilkhani R A. Journal of Molecular Structure, 2015, 1098: 21-25
[15]
Donohue J, Caron A, Goldish E, et al. Journal of the American Chemical Society, 1961, 83(18): 3748-3751
[16]
Steudel R. Zeitschrift Für Naturforschung B, 1983, 38 (5): 543-545
[17]
Warren D S, Gimarc B M. The Journal of Physical Chemistry, 1993, 97 (16): 4031-4035
[18]
Greenwood N N, Earnshaw A. Chemistry of the Elements. 2nd ed. Oxford: Pergamon Press, 1998
[19]
Steudel R, Mäusle H-J. Zeitschrift für anorganische und allgemeine Chemie, 1979, 457 (1): 165-173
[20]
Steudel R, Foerster S, Albertse N J. ChemInform,1991, 22 (50): 7-8
[21]
Schmidt M, Wilhelm E. Inorganic and Nuclear Chemistry Letters,1965, 1(2): 39-41
[22]
Kpf H, Block B, Schmidt M, et al. Chemische Berichte, 1968, 101 (1): 272-276
[23]
Schmidt M, Block D C B, Block D C H D, et al. Angewandte Chemie, 1968, 80(16): 660
[24]
Schmidt M, Block H. Zeitschrift für anorganische und allgemeine Chemie, 1971, 385(1/2): 119-122
[25]
Kawada I, Hellner E. Angewandte Chemie International Edition,1970, 9 (5): 379
[26]
Steudel R, Schuster F. Journal of Molecular Structure,1978, 44 (2): 143-157
[27]
Benson S W. Chemical Reviews, 1978, 78(1): 23-25
[28]
Steudel R, Reinhardt R, Sandow T. Angewandte Chemie International Edition in English, 1977, 16(10): 716
[29]
Steudel R, Steidel J, Pickardt J, et al. Chemischer Informationsdienst, 1980, 11 (27): 7-8
[30]
Lau G E, Cosmidis J, Grasby S E, et al. Geochimica Et Cosmochimica Acta, 2017,200: 218-231
[31]
Warren B, Burwell J. The Journal of Chemical Physics, 1935, 3(1): 6-8
[32]
Abrahams S C, Kalnajs J. Acta Crystallographica, 1955, 8 (8): 503-506
[33]
Rettig S J, Trotter J. Acta Crystallographica, 2010, 43 (12): 2260-2262
[34]
Ni Z Y, Liu H C, Xia J L. Research in Microbiology, 2014, 165(8): 639-646
[35]
张仿刚, 徐宾. 化学教育, 2014, 35 (9): 84-87
[36]
Caron A, Donohue J. Acta Crystallographica, 2010, 18(3): 562-565
[37]
Pastorino C, Gamba Z. Chemical Physics, 2001, 273 (1): 73-76
[38]
Becucci M, Bini R, Castellucci E, et al. Journal of Physical Chemistry B, 1997, 101(12): 2132-2137
[39]
Goldsmith L M, Strouse C E. Chemischer Informationsdienst, 1978, 9(8): 7808
[40]
Templeton L K, Templeton D H, Zalkin A. Inorganic Chemistry, 1976, 15 (8): 1999-2001
[41]
Rosenfield R E, Parthasarathy R. Journal of the American Chemical Society, 1974, 96(6): 1925-1930
[42]
Gallacher A C, Pinkerton A A. Acta Crystallographica Section C, 1993, 49 (1): 125
[43]
Burwell A W. Process of desulfurizing crude petroleum: US, US738656 A. 1903-08-09
[44]
Donald E. Journal of the American Chemical Society,2002, 87 (6): 1395-1396
[45]
Muthmann W X. Crystalline Materials, 1890, 17 (1): 336
[46]
Meyer B. Elemental Sulfur: Chemistry and Physics. New York: Interscience, 1965: 71
[47]
Meyer B. Chemical Reviews, 1964, 64 (4): 429-451
[48]
Steudel R, Holz B. Zeitschrift Für Naturforschung B, 1988, 43(5): 581-589
[49]
Bressan M, Morvillo A. Journal of Organometallic Chemistry,1986, 304 (1): 267-269
[50]
Bacon R F, Fanelli R. Industrial & Engineering Chemistry,2002, 34 (9): 1043-1048
[51]
Lau G E, Cosmidis J, Grasby S E, et al. Geochimica Et Cosmochimica Acta, 2017, 200: 218-231
[52]
Schmidt M, Wilhelm E. Journal of the Chemical Society D Chemical Communications,1970, 17: 1111-1112
[53]
Steudel R, Bergemann K, Buschmann J, et al. Inorganic Chemistry, 1996, 35 (8): 2184-2188
[54]
Zysman-Colman E, Leste-Lassere P, Harpp D N, et al. Journal of Sulfur Chemistry, 2008, 29 (3/4): 309-326
[55]
Schmidt M, Wilhelm E. Inorganic and Nuclear Chemistry Letters, 1965, 1(2): 39-41
[56]
Tuinstra F. The Journal of Chemical Physics, 1967, 46 (7): 2741-2746
[57]
Schmidt M, Block B, Block H D, et al. Angewandte Chemie International Edition, 1968, 7(8): 632-633
[58]
Steudel R, Steidel J, Reinhardt R. Zeitschrift Für Naturforschung B, 1983, 38(12): 1548-1556
[59]
Steudel R, Steidel J, Sandow T, et al. Zeitschrift Für Naturforschung B, 1978, 33: 1198
[60]
Sandow T, Steidel J, Steudel R. Angewandte Chemie, 1982, 94(10): 782-783
[61]
Abraha A, Williams D E. Inorganic Chemistry, 1999, 38 (19): 4224-4228
[62]
Steidel J, Steudel R. Journal of the Chemical Society, 1982, (22): 1312
[63]
Steude R, Steidel J, Sandow T. Zeitschrift Für Naturforschung B, 1986, 41 (8): 951-957
[64]
Schmidt M, Wilhelm E. Angewandte Chemie International Edition in English, 1966, 5 (11): 964-965
[65]
Kutoglu A, Hellner E. Angewandte Chemie International Edition, 1966, 5 (11): 965
[66]
Steidel J, Steudel R, Kutoglu A. Ztschrift für anorganische und allgemne Chemie, 1981, 476 (5): 171-178
[67]
Kutoglu A, Hellner E. Angewandte Chemie, 1966, 78 (22): 1021
[68]
Berkowitz J, Marquart J R. Journal of Chemical Physics, 1963, 39(2): 275-283
[69]
Schmidt M, Knippschild G, Wilhelm E. Berichte der Deutschen Chemischen Gesellschaft, 1968, 101 (1): 381-382
[70]
Schmidt M. Angewandte Chemie, 1973, 85 (11): 474-484
[71]
Schmidt M, Block D C B, Block D C H D, et al. Angewandte Chemie, 1968, 7 (8): 632-633
[72]
Schmidt M, Wilhelm E. Zeitschrift für Naturforschung B, 1970, 25 (12): 47-59
[73]
Schmidt M, Block B, Block H D. et al. Angewandte Chemie International Edition, 1968, 7 (8): 632-633
[74]
Hunsicker S, Jones R O, Gantefo R G. Journal of Chemical Physics, 1995, 102(15): 5917-5936
[75]
Giolando D M, Rauchfuss T B, Wilson S R. Journal of the American Chemical Society, 2002, 106(21): 6455-6456
[76]
Schmidt M, Wilhelm E. Angewandte Chemie, 1966, 78 (22): 1020
[77]
Schmidt M, Wilhelm R N E, Debaerdemaeker T, et al. Zeitschrift für anorganische und allgemeine Chemie,1974, 405 (2): 153-162
[78]
Steudel R, Maeusl E J. Chemischer Informationsdienst,1978, 9: 951-958
[79]
Mäusle H J, Steudel R. Zeitschrift für anorganische und allgemeine Chemie, 1980, 463 (1): 27-31
[80]
Sandow T, Steidel J, Steudel R. Angewandte Chemie,1982, 94 (10): 782-783
[81]
Steudel R, Schumann O, Buschmann J, et al. Angewandte Chemie International Edition, 1998, 37 (17): 2377-2378
[82]
Steudel R, Holz B. Zeitschrift für Naturforschung B, 2015, 43(5): 581-589
[83]
Steudel Ralf. Topics in Current Chemistry, 1982, 102 (5): 177
[84]
Steudel R, Mäusle H J. Angewandte Chemie International Edition, 1979, 18 (2): 152-153
[85]
Steudel R, Strauss E M. Angewandte Chemie International Edition in English, 1984, 23(5):362-363
[86]
Ward A T. Journal of Physical Chemistry, 1968, 72 (12): 4133-4139
[87]
Plašienka D A, Cifra P, Martoňák R. Journal of Chemical Physics, 2015, 142 (15): 154502
[88]
Ludwig R, Behler J, Klink B, et al. Angewandte Chemie, 2002, 114 (17): 3331-3335
[89]
Meyer B. Chemical Reviews, 1976, 76 (3): 367-388
[90]
Prins J A, Schenk J, Hospel P A M. Physica, 1956, 22 (6-12): 770-772
[91]
Prins J A, Schenk J, Wachters L H J. Physica, 1969, 23 (6-10): 746-752
[92]
Lind M D, Geller S. Journal of Chemical Physics,1969, 51 (1): 348-353
[93]
Geller S, Lind M D. Science, 1967, 155 (3758): 79-80
[94]
Steudel R. Angewandte Chemie International Edition in English,1975, 14 (10): 655-664
[95]
Tuinstra F. Physica,1967, 34 (1): 113-125
[96]
Smith A. Proceedings of the Royal Society of Edinburgh, 1904, 24: 342-343
[97]
Kleinberg J, Taebel W A, Audrieth L F. The Journal of Chemical Physics, 1939, 11 (7): 151
[98]
Tuinstra F. Physica, 1967, 34(1): 113-125
[99]
Ezzine M, Pellegatti A, Minot C, et al. New Journal of Chemistry,1998, 22 (12): 1505-1514
[100]
Liebermann C, Natanson S. Berichte Der Deutschen Chemischen Gesellschaft, 1980, 13(2):1575-1579
[101]
Steudel R, Rebsch M. Angewandte Chemie International Edition, 2010, 11(4): 302-303
[102]
Miltenburg J C V, Fourcade J, Ezzine M, et al. The Journal of Chemical Thermodynamics, 1993, 25 (9): 1119-1125
[103]
Steudel R, Holdt G, Young A T. Journal of Geophysical Research, 1986, 91(B5): 4971-4977
[104]
Steudel R. ChemInform,1988, 19 (34): 581-589
[105]
Seff K. The Journal of Physical Chemistry B, 2002, 77(7): 2601-2605
[106]
Buchler J. Angewandte Chemie, 1966, 78 (22): 1021
[107]
Rau H, Kutty T R N, Guedesdecarvalho J. Journal of Chemical Thermodynamics,1973, 5 (2): 291-302
[108]
Meyer C B, Stroyer-Hansen T, Jensen D, et al. Journal of the American Chemical Society,1971, 93 (4): 1034-1035
[109]
Rosen B. Spectroscopic Data Relative to Diatomic Molecules. Oxford: Pergamon, 1970
[110]
Sewzyk P, Erdmann W. Sulfur evaporator: US, US20090007482 A1, 2009-01-08
[111]
Braune H, Steinbacher E. Zeitschrift für Naturforschung A, 1952, 7 (7): 486-492
[112]
Meyer B, Stroyer-Hansen T, Oommen T V. Journal of Molecular Spectroscopy, 1972, 42 (2): 335-343
[113]
Berkowitz J, Lifshitz C. The Journal of Chemical Physics, 1969, 50(10): 4245-4250
[114]
Meyer B, Stroyer-Hansen T. Journal of Physical Chemistry, 1972, 76 (26): 327-331
[115]
Brabson G D, Andrews L, Mielke Z. Journal of Physical Chemistry, 1991, 95(1): 79-86
[116]
Abboud J L M, Esseffar M, Herreros M, et al . The Journal of Physical Chemistry A,1998, 102(41): 7996-8003
[117]
Sugiyama T, Suzuki Y, Takeuchi T. Journal of Chromatographic Science, 11(12): 639-641
[118]
Hess B A, Schaad L J. Journal of the American Chemical Society, 1973, 95 (12): 3907-3912
[119]
Sun C W, Chen Z W, He Z G, et al. Extremophiles, 2003, 7 (2): 131-134
[120]
Wong M W, Steudel R. Chemical Physics Letters, 2003, 379(1/2): 162-169
[121]
Krebs K, Beine H. Zeitschrift für anorganische und allgemeine Chemie, 1967, 355 (3/4): 113-119
[122]
Wiewiorowski T K, Parthasarathy A, Slaten B L. Journal of Physical Chemistry, 1968, 72 (6): 1890-1892
[123]
君轩.世界橡胶工业, 2011,38 (1): 45-46
[124]
李文灿. 不溶性硫磺的合成、改性及其对橡胶性能的影响. 青岛: 青岛科技大学硕士学位论文, 2014
[125]
Kerker M, Daby E, Cohen G L. et al. The Journal of Physical Chemistry, 1963, 67 (10): 2105-2111
[126]
Hamada S, Kudo Y. Bulletin of the Chemical Society of Japan,2006, 52 (4): 1063-1066
[127]
Bolotova G I. Chemistry & Technology of Fuels & Oils,1974, 10 (5): 414-417
[128]
Thackray M. Journal of Chemical & Engineering Data, 1970, 15 (4): 495-497
[129]
王柳英, 邱祖民, 邱俊明, 等. 化工科技, 2006(6): 49-53
[130]
Spencer B H. Process of eliminating sulfur from the sulfur-containing constituents of petroleum: US, US809087 A. 1906-01-02
[131]
贺宗昌, 邵娜.山东化工, 2005 (4): 35-37, 42
[132]
李发全. 一种不溶性硫磺的生产方法及不溶性硫磺:中国,CN111547684A. 2020-08-18
[133]
由文颖, 张玉清, 周集义, 等. 橡胶工业, 2007, 54 (3): 163-165
[134]
王勇, 付建建, 贾建福, 等.当代化工, 2016(11): 2552-2555