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知识介绍
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| 锇催化烯烃双羟基化的反应原理与立体选择性 |
| 邵海云 |
| 上海闵行区友爱实验中学 201109 |
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| Reaction Principle and Stereoselectivity of Osmium Catalyzing Dihydroxylation of Alkene |
| SHAO Haiyun |
| Youai Experimental Middle School of Minhang District of Shanghai 201109 |
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摘要：介绍了四氧化锇催化不对称烯烃双羟基化的反应原理和以N-甲基吗啉-N-氧化物（N-methylmorpholine-N-oxide,NMO）、铁氰化钾K3[Fe（CN）6] 为氧化剂时烯烃双羟基化反应的催化循环；此外,还介绍了该催化反应立体选择性的机理和一些研究进展以及催化体系中手性配体的选择。
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| 关键词： 四氧化锇,
烯烃双羟基化反应,
立体选择性
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| 引用本文: |
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邵海云. 锇催化烯烃双羟基化的反应原理与立体选择性[J]. 化学教育（中英文）, 2007, 28(12): 6-9,12
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