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Chinese Journal of Chemical Education  
  Chinese Journal of Chemical Education--2017, 38 (10)   Published: 18 May 2017
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Chinese Journal of Chemical Education. 2017, 38 (10): 0-0.
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Analysis of Damping Phenomenon and Indoor Dehumidification Based on Principles of Physical Chemistry

ZHANG Ting
Chinese Journal of Chemical Education. 2017, 38 (10): 1-3. ;  doi: 10.13884/j.1003-3807hxjy.2016110063
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From the perspective of physical chemistry, this paper analyzed the damping phenomenon in daily life, and dissected the principle of physical chemistry in indoor dehumidification by taking the cooled dehumidifier unit, air-conditioning and rotary-type dehumidifier as example. Guiding the students towards see life under the vision of physical chemistry could help students learn to discern and analyze the essentials of life, improve their ability of logical analysis, overcome difficulties in learning physical chemistry and increase students' learning interests as well.

Construction and Exploration of Modular-Based Curriculum System for Chemistry Specialty in Application-Oriented Universities

ZENG Zao, ZENG Bing-Fang, LI Jin-Hai, SHU Qun-Wei
Chinese Journal of Chemical Education. 2017, 38 (10): 4-9. ;  doi: 10.13884/j.1003-3807hxjy.2016100010
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To improve teaching quality and cultivate applied talents, modular teaching reform is an effective way. Based on the analysis of the current situation of chemistry specialty and the demands of industry for application-oriented universities, the curriculum system of “platform+module” and “double modules” were put forward by the integration of curriculum structure and contents. Then, the curriculum setting, curriculum contents, teaching methods and teaching evaluation were explored and practiced respectively.

Promote Teaching Effectiveness of Physical Chemistry Using Course Thesis

ZHANG Shu-Yong
Chinese Journal of Chemical Education. 2017, 38 (10): 10-13. ;  doi: 10.13884/j.1003-3807hxjy.2017020028
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The advantages and shortcomings of the former reform in course thesis were analyzed. Based on the objective-based education strategy, a systemic design of course thesis for physical chemistry teaching was made. The practice details for course thesis of physical chemistry in Shandong University and the effectiveness of the reform were introduced. It is of significance for future reform of course thesis.

Strategy for Drawing Structural Units of Common Carbohydrates

WANG Rong-Min, WANG Jian-Feng, WANG Qian-Qian, Qian Li-Zhong, HE Yu-Feng
Chinese Journal of Chemical Education. 2017, 38 (10): 14-19. ;  doi: 10.13884/j.1003-3807hxjy.2016120045
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Carbohydrates (saccharides) are very important in life action. They are abundant in nature as stable structure. In past decades, saccharide-based compounds and materials have been paid more and more attention in chemistry, biology, medicine and materials. However, the part structural formula of saccharide was wrong in some publications, which cause confusion to readers. In this paper, based on discussing the chair conformation of cyclohexane, the strategy on deducing and drawing structural units of monosaccharide, oligosaccharide and polysaccharide has been summarized, which is very useful to understand related contents in publications. It is also very useful to authors for drawing related structures.

Judging Influence of Concentration on Electrode Potential by Chemical Equilibrium Principle

LI Xin-Ai
Chinese Journal of Chemical Education. 2017, 38 (10): 20-21. ;  doi: 10.13884/j.1003-3807hxjy.2016100036
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The effect of concentration on electrode potential could be made qualitative statements according to the chemical equilibrium principle. When the concentration of a substance (one of the redox pair, both of them, or the related ion) have changed, the Nernst equation and chemical equilibrium principle can get the same conclusion, but the latter is more simpler.

Incorporation of Interesting Experiments into Polymer Chemistry Laboratory Course

ZHANG An-Qiang, WU Shui-Zhu, ZHAO Ying, LUO Mei-Xiang
Chinese Journal of Chemical Education. 2017, 38 (10): 22-25. ;  doi: 10.13884/j.1003-3807hxjy.2016110072
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As the traditional polymerization experiments in the polymer chemistry laboratory course are often time-consuming, and there are many waiting time during the polymerization process, several less time-consuming and interesting experiments related with the fundamentals of polymer chemistry, such as PVA gel experiment, interfacial polymerization of nylon-66, and water-absorption properties of sodium polyacrylate resins (artificial snow experiment), were introduced to fill these time slots, thus the total class hours would not be increased. In recent years, the students' feedback on teaching showed that these interesting experiments were well received by the students and greatly enhanced the students' learning interests.

Combined Experiments Teaching for Polymer Materials Specialty

YU Qing-Bo, LI Xian-Hua
Chinese Journal of Chemical Education. 2017, 38 (10): 26-29. ;  doi: 10.13884/j.1003-3807hxjy.2016090085
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Two combined experiments about polymer materials have been developed. One was preparation of g-C3N4/PANI and the study of catalytic performance. The other was preparation and study of porous g-C3N4/PANI. By using the ways of literature, the experiment scheme was determined. The g-C3N4 (porous g-C3N4) was prepared by calcinations of dicyandiamide, and then the composites were obtained by an interfacial polymerization method. On the basis of structural characterization of the obtained materials, the catalytic performance and its influencing factors were studied. These experiments gathered instrumental analysis,polymer materials preparation and physical performance analysis in one. This could not only improve students' experimental ability, but also link knowledge points and provide support for well-rounded talents.

Application of Sunlight in Experiment Design for Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization

LUO JV-Xiang, QIU Dong-Mei, SU Zhi-Zhong
Chinese Journal of Chemical Education. 2017, 38 (10): 30-33. ;  doi: 10.13884/j.1003-3807hxjy.2016080021
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As a new attempt to the aim of training practical talents, the comprehensive polymer chemistry experiment of sunlight induced reversible addition-fragmentation chain transfer (RAFT) polymerization was designed base on the idea of inquiry teaching. The RAFT polymerization of 2-vinylpyridine was successfully carried out under the irridation of sunlight in the only presence of S-1-dodecyl-S'-(α,α″-dimethyl-α″-aceticacid). The sunlight was applied ingeniously in the RAFT polymerization. This study found that the RAFT polymerization had obvious phenomena and the experiment could be performed in an easier way.

Comprehensive Chemistry Experiment:Template Preparation of Graphite Carbon Nitride,Characterization and Performance Evaluation

ZHAO Ya-Ping, YANG Bo, JI Jun-Chao, ZHANG Shuai, BIAN Shao-Wei, SHEN Li, XIAN Chun-Ying
Chinese Journal of Chemical Education. 2017, 38 (10): 34-38. ;  doi: 10.13884/j.1003-3807hxjy.2016100060
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Graphite carbon nitride was prepared from simple raw materials (melamine, silicon sol) using a template method. The structure and morphology of products were characterized and analyzed. The photocatalytic degradation of methylene blue testing was used to evaluate the visible light catalytic properties of graphite carbon nitride, and the degradation reaction kinetics equation and the degradation rate constant were obtained.Students can learn about the template method in controllable preparation of nonmaterialby doing the preparation experiment and their understanding of the structure and properties of light catalytic materials can be deepenedby doing the testing and characterization of the products. The experiment involves the multiple disciplines, which can broaden students' knowledge horizon and cultivate their scientific research innovation ability.

Exploration and Practice of Green Innovative Organic Chemistry Experiment

WU Cheng-Ming, QIAN Shan, ZHOU Jia
Chinese Journal of Chemical Education. 2017, 38 (10): 39-42. ;  doi: 10.13884/j.1003-3807hxjy.2016110028
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The experiment course contents of organic chemistry were reformed by Hanjiang Normal University. A series of green measures with respect to experimental raw materials, solvents, catalysts, products and devices were put forward, and the organic chemistry experiment course were restructured. Through the reform of course contents, not only the laboratory safety was improved, but also the students' environmental consciousness and innovative ability were cultivated.

Comprehensive Experiment: Synthesis and Properties of pH-Responsive Acrylic Acid/Styrene/2-Ethylhexyl Acrylate Copolymer Hydrogel

WEN Jia-Xin, LIU Yun-Xia, YAO Jian-Yu, DUAN Yi-Qin
Chinese Journal of Chemical Education. 2017, 38 (10): 43-46. ;  doi: 10.13884/j.1003-3807hxjy.2016070075
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The acrylic acid/styrene/2-ethylhexyl acrylate copolymer hydrogel was prepared by emulsion polymerization method, and was characterized by fourier transform infrared spectroscopy (FTIR). The influence of pH value on the swelling ratio of the hydrogel was investigated. The thiourea sustained-release system was synthesized by the hydrogel. The results showed that the hydrogel with pH-responsive and excellent sustained-release property had much higher swelling ratio in alkaline conditions than those in neutral or acidic conditions. The experimental process was designed as a comprehensive experiment for higher vocational students, and the practical explorations were carried out. The results showed that it had significant effect on improving students' professional comprehensive ability, broadening their professional vision, and training their creative and scientific thinking.

Effect of Adsorbent on Column Chromatography to Separate Fluorescent Yellow and Methylene Blue BB

GUO Qiao-Xia, ZHOU Jing, YUAN Gui-Mei, YU Xin, ZHAO Liang, ZHANG Min, LIU Zhi-Chang, SHEN Bao-Jian
Chinese Journal of Chemical Education. 2017, 38 (10): 47-52. ;  doi: 10.13884/j.1003-3807hxjy.2016070104
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The type of adsorbent is one of the most important factors in column chromatography separation. Several common stationary phases have been adopted to analyze their influence on the separation effect of fluorescent yellow and methylene blue BB, such as silica gel, alkaline alumina, neutral alumina, and acidic alumina, etc. The acid distribution and pore distribution of the adsorbent were characterized by NH3-TPD and N2 adsorption desorption respectively. The molecular size of fluorescent yellow and methylene blue was calculated using density functional method. The relationship between the acidity, the structure of the adsorbent and the separation efficiency was also investigated. Experimental results showed that the separation effect of silica gel was better than that of neutral alumina. In addition, fluorescent yellow was eluted firstly when silica gel was used as adsorbent, which was contrary to results when neutral alumina was employed. This process was helpful for students to clearly understand the function of stationary phase and column chromatography. And scientific research could also make sense for the cultivation of earnest scientific attitude and ability to analyze and solve problems.

Silica Gel-Catalyzed and Microwave-Irradiated Preparation of Aromatic Amide Under Solvent-Free Condition

GONG Xue
Chinese Journal of Chemical Education. 2017, 38 (10): 53-55. ;  doi: 10.13884/j.1003-3807hxjy.2016070046
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Silica gel-catalyzed and microwave-irradiated preparation of N-phenylbenzamide under solvent-free condition has been developed as a representative example for the amidation reaction. This experiment utilized chromatography-used silica gel as an environmentally benign catalyst, leading to high catalytic efficiency. Such an amide preparation with benzoic acid and aniline performed by microwave-heating at 120 ℃ in the absence of solvent with a yield greater than 90% within 10 min, was quite atom economical and energy efficient. Therefore, it represented a good example of green chemistry in action.

Problems and Suggestions for Pre-Service Chemistry Teachers in Teaching Ethanol Based on Perspective of Context-Setting

WU Lu-Lu, LIU Bing, XIU Ming-Lei
Chinese Journal of Chemical Education. 2017, 38 (10): 56-61. ;  doi: 10.13884/j.1003-3807hxjy.2016060080
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Based on classroom observation, the problems of context-setting in teaching ethanol by pre-service chemistry teachers have been analyzed from four aspects including introduction of class, physical properties, structure and chemical properties of ethanol. And then, some suggestions about how to set context were put forward.

Integration of Multiple Knowledge in Teaching of Pharmaceutical Preparation Engineering

YANG Rong, ZHONG Shi-Hua
Chinese Journal of Chemical Education. 2017, 38 (10): 62-64. ;  doi: 10.13884/j.1003-3807hxjy.2016100020
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In order to improve the teaching quality of the course of pharmaceutical preparation engineering, the knowledge of physical chemistry could be integrated into this course teaching. This paper introduced the integration of “saturated vapor pressure on curved liquid surface”in physical chemistry into the course teaching taking the “spray drying technology” as example, and evaluated the teaching effect of multiple knowledge integration according to the final assessment.

Integrated Teaching of Natural Medicinal Chemistry and Pharmaceutical Spectroscopic Analysis

HE Lin, LI Rui-Yan, TIAN Hai-Ying, LI Wen-Juan, WANG Tao
Chinese Journal of Chemical Education. 2017, 38 (10): 65-68. ;  doi: 10.13884/j.1003-3807hxjy.2016110083
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This paper analyzed the feasibility of the integration of natural medicinal chemistry and spectrum analysis courses,expounded the implementation of curriculum integration in five aspects, such as effective communication between different disciplines, integration of teaching contents, enriching the teaching methods, extension of teaching contents, optimization of evaluation system, etc. This paper also discussed the issues that required attention in order to set up a solid foundation for the further guidance of course teaching for natural medicine chemistry and spectrum analysis courses.

Quantum Chemistry Gaussian Software Assisting Teaching of University Engineering Courses: Energy, Environment and Chemical Engineering as Examples

LIU Yang-Xian
Chinese Journal of Chemical Education. 2017, 38 (10): 69-72. ;  doi: 10.13884/j.1003-3807hxjy.2016110077
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Applications of quantum chemistry gaussian software in the teaching of university engineering courses such as energy, environment and chemical engineering were introduced, which was also described in detail by combining with the three examples: elementary reaction of hydroxyl radical with ozone, elementary reaction of nitric oxide with hydroxyl radical and reaction pathway of hydrogen production from supercritical water gasification of formic acid. Practice showed that by using this method the engineering students could afford insight into the intrinsic laws of chemical reaction and the nature of problem on the micro-level, which can deepen the students' understanding of “micro-chemical knowledge” and stimulate the enthusiasm of the students to explore the deep-level “micro-chemical knowledge”, thus to achieve perfect teaching effect.

Developing Learning Progression Framework and Empirical Research on the Ideas of the Nature of Models

ZHANG Jing, DING Lin, GAO Jia-li
Chinese Journal of Chemical Education. 2017, 38 (10): 73-78. ;  doi: 10.13884/j.1003-3807hxjy.2017010060
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View of the nature of models was the key element of scientific literacy, which was the core of science education. Based on the previous research, the learning progression framework on the ideas of the nature of models has been developed. Through an investigation on 381 students including secondary school students and undergraduates, this research showed that many students had misconception about models, especially in the dimension of “relation between models and entity”.

Zeta Potential Calculation with Electrophoresis Method

WANG Yu, SHENG Shou-Ri, ZHANG Xiao-Liang
Chinese Journal of Chemical Education. 2017, 38 (10): 79-81. ;  doi: 10.13884/j.1003-3807hxjy.2016060008
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The calculation formula of electro-kinetic potential (also called zeta potential) with electrophoresis method was confused in current textbooks of physical chemistry and experiments in physical chemistry due to using different systems of units. In this work, the physical meanings of the different dielectric constants and the right calculation formula of zeta potential under CGSE units and SI units were discussed based on the literature survey. Moreover, it was summarized with the unified calculation formula of zeta potential for all the colloidal particles along with the calculated examples verification.

Chinese Journal of Chemical Education. 2017, 38 (10): 9-9.
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Chinese Journal of Chemical Education. 2017, 38 (10): 25-25.
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Chinese Journal of Chemical Education. 2017, 38 (10): 42-42.
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