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Chinese Journal of Chemical Education  
  Chinese Journal of Chemical Education--2018, 39 (16)   Published: 18 August 2018
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Chinese Journal of Chemical Education. 2018, 39 (16): 0-0.
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Biomimetic Preparation of ZnO Nanoparticles and Their Antibacterial Activity

CAI Ai-Jun, GUO Ai-Ying, WANG Xiu-Ping
Chinese Journal of Chemical Education. 2018, 39 (16): 1-4. ;  doi: 10.13884/j.1003-3807hxjy.2017080045
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Due to the high-efficiency, simplicity, and environmental-friendly properties, biomimetic preparation of ZnO nanoparticles (NPs) has received considerable attention.In this paper, we discussed the development in the field of biomimetic preparation of ZnO NPs and their antibacterial activity.

Teaching Practice of Inorganic and Analytical Chemistry Based on MOOC and SPOC

LI Hui-Hui, XIAO Xiang-Ping, WU Cheng-Chun, WANG Yun
Chinese Journal of Chemical Education. 2018, 39 (16): 5-8. ;  doi: 10.13884/j.1003-3807hxjy.2017090064
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This paper discussed the working point and the main teaching problems of MOOC construction by taking the construction and teaching practice of inorganic and analytical chemistry MOOC as an example. Purposeful and oriented MOOC construction and teaching practice were carried out. New curriculum teaching system based on students' self-learning was structured. Students would obtain the autonomy of learning by the improvement of teaching method and examination.

Mathematical Proof of the Equivalence of Different Expressions of State Function Property

MA Gang, YU Yang, YANG Lu-Juan, DU Bao-An
Chinese Journal of Chemical Education. 2018, 39 (16): 9-11. ;  doi: 10.13884/j.1003-3807hxjy.2017100060
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This paper describes the mathematical expressions of state function property. Through strict mathematical reasoning, the three mathematical expressions of state function property are proved to be equivalent to each other. Their equivalence to Maxwell's equations is also proved to be true. This means that applying state function property can be a simple way to solve a real problem.

Analysis and Discussion on Related Problems of Surface Tension

LIU Yu-Chen, WANG Yi
Chinese Journal of Chemical Education. 2018, 39 (16): 12-15. ;  doi: 10.13884/j.1003-3807hxjy.2017120091
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As an important concept of surface phenomenon, surface tension of liquid should be explained in a more detail and comprehensive way than in current physical chemical textbooks. Therefore, by means of many three-dimensional graphs, the questions about the nature, direction, and phase interface exerting force of surface tension of liquid were expounded for the addition of an appropriate supplement to content uncovered in textbooks so as to reduce beginners' difficulty in the understanding of concepts in this paper.

Enlightenment of Aalborg PBL Mode on Improving Teaching and Learning Effectiveness of Organic Spectral Analysis Course

SHU Peng-Hua, JV Zhi-Yu, XU Zhi-Hong, WU Chang-Zeng
Chinese Journal of Chemical Education. 2018, 39 (16): 16-20. ;  doi: 10.13884/j.1003-3807hxjy.2018020065
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This paper summarizes the main problems existing in the organic spectral analysis course, and analyzes the basic characteristics of Aalborg PBL mode as well as the necessity and feasibility of applying it into organic spectral analysis course teaching. A teaching reform proposal based on Aalborg PBL mode is put forward from four aspects such as period distribution, teaching contents, teaching methods and assessment manners, which aims to improve the effectiveness of teaching and learning.

An Optimized Reaction Device for Substitution Reaction of Methane and Chlorine

YAN Sheng-Zhong, CHEN Lin, WANG Ke-Wang, BAI Yun-Shan, ZHOU Qing
Chinese Journal of Chemical Education. 2018, 39 (16): 21-24. ;  doi: 10.13884/j.1003-3807hxjy.2017090009
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For the disadvantages of the traditional device for substitution reaction of methane & chlorine, such as environment friendless, complex reactor, difficulty in quantifying, an optimized and easy assembled apparatus was designed by our group, which achieves the greening of the reaction, miniaturization and integration of the apparatus as well as the quantifying and controllability of the reaction.

Experiment Teaching Design of Oxidation Decontamination Technologieson Paper Archives

OU Xiu-Hua, YANG Fu-Wei, ZHANG Rui-Xiang
Chinese Journal of Chemical Education. 2018, 39 (16): 25-29. ;  doi: 10.13884/j.1003-3807hxjy.2016090080
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In order to enhance the understanding of the basic theory on oxidation decontamination technologies, arouse the enthusiasm and initiative learning on paper archives experiment and promote practical ability and experimental innovation, experiment teaching of oxidation decontamination technologies on paper archives is designed. This design is different from common method in reference books. It not only wipes off the stain on paper archives, but deacidifies and reinforces paper archives. Effect evaluation of decontamination considers paper and file handwriting. This teaching design embodies research-based teaching on archives preservation technology science.The results showed that the reflecting relevant basic theoretical knowledge was strengthened and the method of experimental operation and data analysis was mastered.

Synthesis of Porous Silica Supported Dual Brönsted Acid-Functionalized Ionic Liquid Catalyst and Application in Catalyzing Preparation of Biodiesel

LI Xue-Qin, XIE Ya-Li, CHENG Jian-Wen, CAO Ling, XUE Lai-Qi
Chinese Journal of Chemical Education. 2018, 39 (16): 30-35. ;  doi: 10.13884/j.1003-3807hxjy.2016030067
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In the college students' innovative research projects, biodiesel was prepared with a green ionic liquid catalyst to clean energy as the breakthrough point. 1-methyl-3-(propyl-3-sulfonyl) imidazolium hydrogensulfate was synthesized and immobilized by impregnating method to the surface of porous silica. Biodiesel has been produced by transesterification of sunflower seed oil with[PSMIM]HSO4/SiO2.The effect of amount of catalyst, reaction temperature, molar ratio and reaction time was investigated. The results of experiment showed that the conversion rate was the highest under transesterification on conditions of reaction time 10 h, reaction temperature 160℃, catalyst dosage 8% and molar ratio of methanol to oil 25:1, and the conversion rate was up to 92.5%.[PSMIM]HSO4/SiO2 were characterized by FTIR, XRD and 13C NMR. Components of biodiesel were analyzed by gas chromatograph (GC). The performance of biodiesel had been conformed to the standards of biodiesel in our country, including the freezing point, density and kinematic viscosity. This project not only has made some achievements in research, but also has promoted the students' innovation and team consciousness, as well as teachers' teaching ability.

Fabrication and Chemical Modification of Functional Polymer Surfaces

LI Jun-Sheng, XU Jun
Chinese Journal of Chemical Education. 2018, 39 (16): 36-39. ;  doi: 10.13884/j.1003-3807hxjy.2017080075
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This article introduces a chemical experiment, the fabrication and chemical modification of functional polymer surfaces, and its teaching idea. The functional polymer surface can be fabricated by phase separation methods. The experiment explored the influence of solvent composition in the precursor on the wettability of the polymer surface. At the same time, click chemical reactions are used to modify the hydrophilic surface. The contact angles of surfaces are measured with static drop method. Using scanning electron microscope (SEM), the surface morphology of the polymer are characterized before and after modification. Results show that with the change of solvent formula, the contact angle varies a lot. This comprehensive experiment integrates chemical basic knowledge, chemical academic frontier and experimental basic skills, which is beneficial to cultivate students' innovative thinking and improve their comprehensive ability.

Application of Flipped Classroom in Experimental Chemistry Teaching Basedon Guided Learning Plan and PBL

YANG Jin-Feng, MA Yan-Mei, LIU Hong, WEI Wen-Zhen, YANG Jian-Rong
Chinese Journal of Chemical Education. 2018, 39 (16): 40-44. ;  doi: 10.13884/j.1003-3807hxjy.2017120038
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This paper attempts to discuss the implementation of the flipped classroom teaching in experimental chemistry courses by means of the integration of the guided learning plan and problem based learning (PBL). To ensure the scientificity and effectiveness of the current flipped classroom practice, a questionnaire survey was conducted. Results showed that the flipped classroom teaching based on the guided learning plan and PBL worked well in developing students' active learning ability, as well as in building an integrated system of three dimensions:knowledge and skills, process and methods and the emotional attitude of experiment. It should be stressed that the teaching reform is effective in improving the teaching quality.

Developing Assessment Literacy of Pre-Service Chemistry Teachers

ZHU Li-Ying, WANG Zu-Hao
Chinese Journal of Chemical Education. 2018, 39 (16): 45-50. ;  doi: 10.13884/j.1003-3807hxjy.2017120015
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The purpose of this study is to develop assessment literacy of pre-service chemistry teachers by taking the course of measurement and evaluation of chemistry teaching, where the key feature was an innovative approach based on the real-world situations. The one-group pretest-posttest design was used, and pre-service chemistry teachers in Zhejiang Normal University were enrolled in the study. The results indicated that course training could improve assessment literacy of pre-service teachers, but there were different effects among dimensions. There were significant effects on the dimension of "Fundamental Concepts","Data Interpretation","Quality Characteristics","Ethics of Evaluation" and "Test Grade". The two formers' ultimate levels were higher, and the three latters' were lower. However, there was no significant difference on the dimension of "Test Design", but the level was high.

Constructing Student-Centered Teaching Mode of Chemical Engineering Specialty Based on Constructivism

NING Hui, LIU Xin-Mei
Chinese Journal of Chemical Education. 2018, 39 (16): 51-56. ;  doi: 10.13884/j.1003-3807hxjy.2017110053
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Based on the theory of constructivism, student-centered teaching mode of chemical engineering specialty was established. Aimed to cultivate outstanding chemical professionals, the theoretical architecture and teaching design were constructed from the aspects of curriculum construction, situational construction, teaching team, teaching evaluation and supporting system, etc. Through teaching practice, it is proved that this kind of teaching mode can stimulate the students' interests in learning and improve the students' learning result.

Inquiry Case Teaching Mode in Teaching of Pharmaceutical Preparation Engineering

YANG Rong, ZHONG Shi-Hua, XIAO Xiao-Ming
Chinese Journal of Chemical Education. 2018, 39 (16): 57-61. ;  doi: 10.13884/j.1003-3807hxjy.2017110100
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The teaching process of inquiry teaching mode of pharmaceutical preparation engineering was practiced and improved through designing and implementing the three stages of teaching flowchart. Meantime, the teaching effect of inquiry teaching mode was evaluated by constructing the quantitative evaluation index, the tripartite evaluation and questionnaire. Finally, the further suggestions were given for the existing problems.

Application of Software Technology in Quantitative Analysis of Near Infrared Spectroscopy

CHEN Su-Bin, HU Zhen, ZHANG Xiao-Qi, REN Wei
Chinese Journal of Chemical Education. 2018, 39 (16): 62-67. ;  doi: 10.13884/j.1003-3807hxjy.2017100073
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To improve the quality of quantitative analysis of near infrared spectroscopy by chemometrics, the application of related algorithms and software tools were comprehensively studied. According to the general process of quantitative analysis of near infrared spectrum, the common algorithms of spectral data preprocessing, abnormal sample detection, sample set division, wavelength selection, model establishment and parameter optimization were discussed in turn, and the basic steps of various mainstream algorithms were given. Then the functions, features and main applications of OMNIC、OPUS、Origin、The Unscrambler X and MATLAB software tools were introduced to provide reference for related technology research and analysis detection work.

Case Teaching of Sequential Modular Method of Analysis and Synthesis forChemical Engineering Process Integrated with Aspen Simulation

XIANG Dong, JIN Tong, FANG Yuan-Ting, CAO Yan
Chinese Journal of Chemical Education. 2018, 39 (16): 68-71. ;  doi: 10.13884/j.1003-3807hxjy.2017090046
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Analysis and synthesis of chemical engineering process is a professional course with very strong practice of chemical engineering, and its main method is the simulation of chemical engineering systems. How to integrate the course with Aspen simulation is the important problem need to be solved in the process of teaching. The integration between sequential modular method of the course and corresponding Aspen simulation will be used as a case teaching, focusing on simulation convergence problems due to the inappropriate selection of tearing streams and unreasonable initial values. This can make the theory teaching of this course more vivid and the learning more easy. Besides, it can also improve students' ability to use Aspen software and solve practical problems, and finally lay a solid foundation for subsequent engineering design.

Theoretical Study About Products of the Birch Reduction

HE Luo
Chinese Journal of Chemical Education. 2018, 39 (16): 72-74. ;  doi: 10.13884/j.1003-3807hxjy.2017110090
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The Birch reduction converts aromatic compounds possessing a benzenoid ring into products derived from 1,4-cyclohexadienes, which has rarely been explicitly concluded in various organic chemistry textbooks. Current mechanisms indicate that the step determining the position of the carbon-carbon double bonds in the product is the protonation of the anion intermediate after capturing two electrons. This article studied the regional selectivity in the protonation step on the base of quantum chemical calculations and reports of other literature. The results demonstrate both qualitatively and quantitatively that the protonation site is mainly the carbon atom with the largest orbital coefficient in the intermediate's HOMO, which means the regional selectivity is resulted from chemical kinetics factors.

Possible Flaw in Experiment Design on Continuous VariationMethod for Determining the Stability Constant of a Complex

WANG Rong, WANG Qing
Chinese Journal of Chemical Education. 2018, 39 (16): 75-77. ;  doi: 10.13884/j.1003-3807hxjy.2017080034
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Determination of the formula and stability constant of a complex by the continuous variation method is a standard experiment for chemistry students in universities. But when the metal to ligand complexation formation is 1:2 or 1:3, the experiment designs in all the experiment textbooks may have the same flaw, which is too few sampling points, or too few solutions being prepared. If the solutions were prepared according to these textbooks, there would be no solution with the metal to ligand ratio which corresponds to the stoichiometry of the complex. With all the points showing good linearity, there would not be enough data to estimate the curve so as to calculate the stability constant. This paper discussed the reason, consequences and solutions of this flaw in this kind of experiment design.

The Summary of Chinese Authors' Papers Published in Journal of Chemical Education During Past Ten Years

ZHAO Man-Jie, ZHENG Min, ZHANG Qin, YIN Du-Lin
Chinese Journal of Chemical Education. 2018, 39 (16): 78-81. ;  doi: 10.13884/j.1003-3807hxjy.2017070026
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By making a statistical analysis of the number of papers, the number of authors, regional distribution, author's company and cooperation situation, and thesis content of Chinese authors' papers that published in the Journal of Chemical Education during 2007-2016, the characteristics of Chinese chemistry education research in recent years was revealed to provide some reference for the training of chemical talents in China and promote international exchange of chemical education in China.

Chinese Journal of Chemical Education. 2018, 39 (16): 15-15.
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